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Intramolecular amidation of sulfamate esters catal

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专利名称:Intramolecular amidation of sulfamate

esters catalyzed by metalloporphyrins

发明人:Chi-Ming Che,Jiang-Lin Liang申请号:US10202581申请日:20020723

公开号:US20040019204A1公开日:20040129

摘要:The present invention relates to novel intramolecular amidation processes forsubstrates such as sulfamate esters using chiral and non-chiral metalloporphyrincomplexes, which can maximize catalytic activity and enhance efficiency, stereoselectivityand speed of amidation of these substrates. The intramolecular amidation of sulfamateester exhibits excellent cis-selectivity, affording cyclic sulfamidates with high ee valuescatalyzed by chiral metalloporphyrin.

申请人:CHE CHI-MING,LIANG JIANG-LIN

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